KEIO RESEARCHERS INFORMATION SYSTEM

Career 【 Display / hide 】

Career 【 Display / hide 】

• 1995.04

  -

  2000.03

  慶應義塾大学 助手（理工学部応用化学科）

• 2000.04

  -

  2005.03

  Assistant Professor

• 2001.09

  -

  2002.09

  アーヘン工科大学 客員研究員

• 2005.04

  -

  2007.03

  Associate Professor, Keio University

• 2007.04

  -

  2012.03

  Associate Professor, Keio University

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Academic Background 【 Display / hide 】

Academic Background 【 Display / hide 】

• 1990.03

  Kyoto University, Faculty of Engineering, 工業化学科

  University, Graduated

• 1992.03

  Kyoto University, Graduate School, Division of Engineering, 分子工学専攻

  Graduate School, Completed, Master's course

• 1995.03

  Kyoto University, Graduate School, Division of Engineering, 分子工学専攻

  Graduate School, Completed, Doctoral course

Academic Degrees 【 Display / hide 】

Academic Degrees 【 Display / hide 】

• 博士（工学）, Kyoto University, 1995.03

Research Areas 【 Display / hide 】

Research Areas 【 Display / hide 】

• Nanotechnology/Materials / Inorganic materials and properties

• Nanotechnology/Materials / Inorganic/coordination chemistry

• Nanotechnology/Materials / Green sustainable chemistry and environmental chemistry

• Nanotechnology/Materials / Inorganic compounds and inorganic materials chemistry

Research Keywords 【 Display / hide 】

Research Keywords 【 Display / hide 】

• Sol-Gel Method

• Fluorochromic Phosphor

• Photoenergy Conversion

• Chemical Sensor

• Layered Metal Hydroxide Materials

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Research Themes 【 Display / hide 】

Research Themes 【 Display / hide 】

• 蛍光体を利用した化学センサの開発, 

  2017.04

  -

  Present

• 外場応答型無機蛍光体材料の開発, 

  2009.04

  -

  Present

• 液液二相系における革新的無機合成, 

  2007.04

  -

  Present

• 色素増感太陽電池電極の構造制御と高効率化, 

  2000.04

  -

  Present

• 層状金属水酸化物の合成と多機能化, 

  2000.04

  -

  Present

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Proposed Theme of Joint Research 【 Display / hide 】

Proposed Theme of Joint Research 【 Display / hide 】

• 液相法（ゾル-ゲル法など）を利用した無機材料のプロセッシング技術の開発

• 無機蛍光体材料を利用した蛍光・化学センシングシステムの開発

Books 【 Display / hide 】

Books 【 Display / hide 】

• Sol-gel processing of fluoride and oxyfluoride materials

  Fujihara S., Handbook of Sol-Gel Science and Technology: Processing, Characterization and Applications, 2018.07

  　View Summary

  Producing fluoride and oxyfluoride materials is not easy because of the potential toxicity of fluorinated compounds and gases. Sol-gel processing has been used to produce fluoride and oxyfluoride materials in two ways. In the first case, the composition is formed from oxide precursors, followed by a reactive treatment in HF to fluorinate the composition. In the second case, trifluoroacetate precursors or metal alkoxides in trifluoroacetic acid are used to form the gel or thin films directly. The principal motivation for using sol-gel routes to prepare glassy fluorides and oxyfluorides is that they have useful optical applications.

  • Access to Document (DOI)

• ゾル－ゲルテクノロジーの最新動向

  FUJIHARA SHINOBU, シーエムシー出版, 2017.07

  Scope: マルチ機能性発光材料（pp.268-276）

• ウェットプロセスによる精密薄膜コーティング技術

  FUJIHARA SHINOBU, 技術情報協会, 2014.08

  Scope: 477-480

• ゾル－ゲル法の最新応用と展望

  FUJIHARA SHINOBU, シーエムシー出版, 2014.02

  Scope: 193-198

• 光学薄膜の最適設計・成膜技術と膜厚・膜質・光学特性の制御

  FUJIHARA SHINOBU, 技術情報協会, 2013.06

  Scope: 415-418

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Papers 【 Display / hide 】

Papers 【 Display / hide 】

• Ni-doping effect on thermoelectric properties of c-axis-oriented CuFeO<inf>2</inf> ceramics

  Hagiwara M., Tato M., Shiojiri D., Iida T., Fujihara S.

  Journal of Alloys and Compounds （Journal of Alloys and Compounds)  905 2022.06

  ISSN  09258388

  　View Summary

  The combined effect of chemical doping and grain orientation on the thermoelectric properties of delafossite-type CuFeO2 ceramics was investigated. Ni was chosen as the dopant, whereas the reactive templated grain growth method was used for the fabrication of grain-oriented bulk ceramics. Nanorods of Ni-doped α-FeOOH with a nominal Ni content of up to 5 mol% were synthesized by the hydrothermal method and were then used as the template to fabricate Ni-doped CuFeO2 ceramics with a preferred c-axis orientation. The electrical conductivity, Seebeck coefficient, and thermal conductivity of the Ni-doped CuFeO2 ceramics along the in-plane direction (perpendicular to the orientation axis) were measured at temperatures between 300 and 1100 K. Ni doping was found to effectively increase the electrical conductivity and decrease the thermal conductivity, whereas it maintained a high Seebeck coefficient of around 400 μV K−1. Consequently, the c-axis-oriented CuFeO2 ceramics doped with 1 and 3 mol% Ni showed an enhanced dimensionless figure of merit of 0.08 at 900 K.

  • Access to Document (DOI)

• Grain-size-insensitive dielectric properties of Sr<inf>0.6</inf>Ba<inf>0.4</inf>Nb<inf>2</inf>O<inf>6</inf> relaxor ferroelectric ceramics with tetragonal tungsten bronze structure

  Tsuchiya M., Fujihara S., Hagiwara M.

  Ceramics International （Ceramics International)  48 （ 5 ） 6819 - 6825 2022.03

  ISSN  02728842

  　View Summary

  The influence of grain size on the dielectric properties of Sr0.6Ba0.4Nb2O6 (SBN60) ceramics with a tetragonal tungsten bronze structure was examined. The conventional and two-step sintering procedures were used to fabricate dense and phase-pure SBN60 ceramics with grain sizes ranging from 2.2 μm to 17.3 μm. In the temperature dependence of the dielectric permittivity, all samples showed a relaxor-like broad dielectric peak with a maximum at around 60 °C. The maximum dielectric permittivity and dielectric maximum temperature of the SBN ceramics were found to be less dependent on the grain size. The reason for the grain-size-insensitive dielectric properties of the SBN60 ceramics is discussed based on the analysis of the dielectric properties and Raman spectra.

  • Access to Document (DOI)

• Redox-induced dual optical switching of CaTiO<inf>3</inf>:Pr³⁺ phosphor nanoparticles synthesized by sol–gel method

  Takahashi H., Hagiwara M., Fujihara S.

  Journal of Sol-Gel Science and Technology （Journal of Sol-Gel Science and Technology)   2022

  ISSN  09280707

  　View Summary

  Red-emitting CaTiO3:Pr3+ phosphor nanoparticles were synthesized by a sol–gel method with a final heat treatment at a low temperature of 650 °C. For comparison, the CaTiO3:Pr3+ phosphor was also synthesized by a conventional solid-state reaction method conducted at 1250 °C. The two kinds of resultant CaTiO3:Pr3+ samples were revealed to differ largely in their microstructure and optical properties. Diffuse reflectance and photoluminescence measurements suggested that the sample from the solid-state reaction possessed a larger number of defects, which would deteriorate the optical properties, due to heating at high temperature. On the other hand, the sol–gel-derived sample exhibited much better optical properties and thus it was used for evaluating optical-switching phenomena upon redox treatments. In photoluminescence, three excitation bands were observed at 265, 335, and 375 nm for the red emission of the CaTiO3:Pr3+ sample, and one of them (375 nm) was more effective for inducing luminescence quenching by a reduction treatment at room temperature. A body color of the CaTiO3:Pr3+ sample was also changed from white to light yellow by the reduction due to the enhanced visible-light absorption. Such the dual luminescence/absorption switching was shown to be reversible with a subsequent oxidation and repeatable with a consecutive redox treatment. [Figure not available: see fulltext.]

  • Access to Document (DOI)

• Fabrication of meso- and macro-porous Y<inf>2</inf>WO<inf>6</inf>:Eu³⁺ phosphor thin films by Pechini-type sol–gel dip-coating method and their characteristic optical properties

  Ye H., Hagiwara M., Fujihara S.

  Journal of Sol-Gel Science and Technology （Journal of Sol-Gel Science and Technology)  100 （ 2 ） 232 - 243 2021.11

  ISSN  09280707

  　View Summary

  Meso- and macro-porous Y2WO6:Eu3+ phosphor thin films were fabricated on silica glass substrates by a Pechini-type sol–gel dip-coating method. Precursor solutions for coating were prepared by mixing aqueous solutions of metal salts, ethylene glycol, and citric acid with water–alcohol solutions of a nonionic triblock copolymer (P-123) employed as a structure-directing agent. The kind of the alcohol solvents (methanol, ethanol, or isopropanol) and the amount of ethylene glycol were systematically examined because they were found to be major factors that could influence the shape and size of pores formed in the resulting thin films. The transmittance for the visible light was decreased in the thin films having macropores due to the light scattering. The red photoluminescence of the Eu3+ ions could be enhanced in these macro-porous thin films, especially from their surface, by a synergetic effect of increased multiple scattering and suppressed internal reflection of the emission light. The relationship between the microstructure and the optical properties of the porous Y2WO6:Eu3+ thin films was then discussed based on the experimental results. [Figure not available: see fulltext.]

  • Access to Document (DOI)

• Fabrication of p-type semiconducting NiCo<inf>2</inf>O<inf>4</inf> thin films using hydroxide nanoplatelet precursors and their application to N749-sensitized photocathodes

  Miyachi M., Hagiwara M., Fujihara S.

  Journal of the Ceramic Society of Japan （Journal of the Ceramic Society of Japan)  129 （ 7 ） 348 - 354 2021.07

  ISSN  18820743

  　View Summary

  NiCo2O4 is promising as one of the p-type oxide semiconductors for practical applications in optoelectronic devices. In this study, we have elaborated NiCo2O4 hexagonal nanoplatelet films and examined their photovoltaic properties. The film fabrication was actually achieved by four steps: the synthesis of hexagonal nanoplatelets of a Ni1/3Co2/3(OH)2 precursor, the dispersion of the nanoplatelets in liquid media, the self-assembly of the nanoplatelets on dipped substrates, and the topological conversion of the hydroxide to the oxide by the heat treatment. The resultant NiCo2O4 thin films had structural features such as the crystallographic (111) orientation, the high specific surface area, and the high light-scattering ability. As a result, the NiCo2O4 thin films loaded with an N749 dye could work effectively as photocathodes in the configuration of dye-sensitized solar cells.

  • Access to Document (DOI)

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Papers, etc., Registered in KOARA 【 Display / hide 】

Papers, etc., Registered in KOARA 【 Display / hide 】

• Development and application of Fluorochromic inorganic phosphors

  Fujihara, Shinobu

  科学研究費補助金研究成果報告書 2019

• Development of chemically responsive imaging materials based on surface control of inorganic phosphors

  Fujihara, Shinobu

  科学研究費補助金研究成果報告書 2015

• Control of magnetic ordering of nanoscale metal and nanoparticle assembly by magnetoelectric effect

  Fujihara, Shinobu

  科学研究費補助金研究成果報告書 2014

• Development of a new synthesis method for functional materials using liquid-liquid biphasic systems

  Fujihara, Shinobu

  科学研究費補助金研究成果報告書 2011

• Surface activation and functionalization of insulating metal oxide materials by nano-scale morphology control

  FUJIHARA, SHINOBU

  科学研究費補助金研究成果報告書 2008

Reviews, Commentaries, etc. 【 Display / hide 】

Reviews, Commentaries, etc. 【 Display / hide 】

• ゲーレナイトの圧電材料としての可能性

  TAKEDA HIROAKI, HOSHINA TAKUYA, TSURUMI TAKAAKI, KODAMA NOBUHIRO, HAGIWARA MANABU, FUJIHARA SHINOBU

  日本電子材料技術協会会報 (日本電子材料技術協会)  47 ( 11 ) 11 - 15 2016.11

  Internal/External technical report, pre-print, etc., Joint Work

• 無機発光材料の構造制御に基づく複合的光学機能の創出

  FUJIHARA SHINOBU

  工業と製品（セラミックデータブック2015/16） (工業製品技術協会)  43 ( 97 ) 71 - 74 2015.12

  Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media), Single Work

• 無機蛍光体への外場応答性付与に基づく新規なイメージング材料の開発

  FUJIHARA SHINOBU

  公益財団法人日本板硝子材料工学助成会成果報告書 (公益財団法人日本板硝子材料工学助成会)   ( 33 ) 158 - 163 2015.08

  Article, review, commentary, editorial, etc. (other), Single Work

• 化学的環境に応答する無機イメージングパウダーの創製

  FUJIHARA SHINOBU

  ホソカワ粉体工学振興財団年報平成26年度 (公益財団法人ホソカワ粉体工学振興財団)   ( 22 ) 68 - 74 2015.05

  Article, review, commentary, editorial, etc. (other), Single Work

• 光機能アセンブリーに基づく蛍光体の新機能開拓

  FUJIHARA SHINOBU

  セラミックス (日本セラミックス協会)  50 ( 3 ) 156 - 159 2015.03

  Article, review, commentary, editorial, etc. (scientific journal), Single Work

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Presentations 【 Display / hide 】

Presentations 【 Display / hide 】

• 層状イットリウム水酸化物の構造制御と蛍光センシング材料への応用

  MORIYAMA SHUN, HAGIWARA MANABU, FUJIHARA SHINOBU

  日本セラミックス協会2018年年会 (東北大学（仙台市）) , 

  2018.03

  , 

  Oral presentation (general), 日本セラミックス協会

• 水熱合成法による金属基板上への(Bi_1/2K_1/2)TiO₃膜の作製と振動発電素子への応用

  HAGIWARA MANABU, SAKURAI RYOTARO, FUJIHARA SHINOBU

  日本セラミックス協会2018年年会 (東北大学（仙台市）) , 

  2018.03

  , 

  Oral presentation (general), 日本セラミックス協会

• 均一な微構造を持つ粒界絶縁型複合キャパシタの作製に向けた単分散導電体-絶縁体core-shellナノ粒子の合成

  INAGAKI TAKUYA, UENO SHINTARO, FUJII ICHIRO, WADA SATOSHI, HAGIWARA MANABU, FUJIHARA SHINOBU

  日本セラミックス協会2018年年会 (東北大学（仙台市）) , 

  2018.03

  , 

  Oral presentation (general), 日本セラミックス協会

• 2相ゾル-ゲル法で合成したYVO₄:Eu³⁺ナノ/マイクロ構造膜によるH₂O₂センシング

  MOTOMIYA KASUMI, HAGIWARA MANABU, FUJIHARA SHINOBU

  日本セラミックス協会2018年年会 (東北大学（仙台市）) , 

  2018.03

  , 

  Poster presentation, 日本セラミックス協会

• 層状イットリウム水酸化物をY源とした固相反応によるデラフォサイト型CuYO₂の合成

  NARUSHIMA SHUNSUKE, HAGIWARA MANABU, FUJIHARA SHINOBU

  日本セラミックス協会2018年年会 (東北大学（仙台市）) , 

  2018.03

  , 

  Poster presentation, 日本セラミックス協会

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Research Projects of Competitive Funds, etc. 【 Display / hide 】

Research Projects of Competitive Funds, etc. 【 Display / hide 】

• Development of Fluorochromic Inorganic Materials and Their Application to Fluorescence Sensing Systems

  2020.04

  -

  2023.03

  MEXT,JSPS, Grant-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (C), Principal investigator

• 金属-有機構造体(MOF)を経由した新規なセラミックスナノ多孔質粒子の製造と応用展開

  2017.12

  -

  2019.03

  公益財団法人大倉和親記念財団, 平成29年度（第48回）研究助成, Research grant, No Setting

• フルオロクロミック無機蛍光体の開発と応用

  2017.04

  -

  2020.03

  Grant-in-Aid for Scientific Research, Research grant, Principal investigator

• 無機蛍光物質の表面制御に基づく化学応答性イメージング材料の開発

  2013.04

  -

  2015.03

  Grant-in-Aid for Scientific Research, Research grant, Principal investigator

• 化学的環境に応答する無機イメージングパウダーの創製

  2013.04

  -

  2014.03

  公益財団法人ホソカワ粉体工学振興財団, 平成24年度研究助成, Research grant, No Setting

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Works 【 Display / hide 】

Works 【 Display / hide 】

• マテリアル科学３

  FUJIHARA SHINOBU

  2010.04

  -

  Present

  , 

  Other, Single

  　View Details

  教材の作成

• マテリアル科学１

  FUJIHARA SHINOBU

  2009.04

  -

  Present

  , 

  Other, Single

  　View Details

  教材の作成

• ZnO色素増感太陽電池の現状と展望

  FUJIHARA SHINOBU

  2008.06

  -

  Present

  , 

  Other, Single

• 無機ナノマテリアルの構造制御による高機能化と光・電子分野への応用

  FUJIHARA SHINOBU

  2008.05

  -

  Present

  , 

  Other, Single

• ケミカルプロセスの特徴を活かした発光材料の創製と応用

  FUJIHARA SHINOBU

  2007.09

  -

  Present

  , 

  Other, Single

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Intellectual Property Rights, etc. 【 Display / hide 】

Intellectual Property Rights, etc. 【 Display / hide 】

• 電極材料、電極及び発光型エレクトロクロミック素子

  Date applied： 特願2013-189096  2013.09 

  Date issued： 第6182727号  2017.08

  Patent, Joint

• 酸化物超電導体の製造方法および酸化物超電導体製造用前駆体

  Date applied： 1996-276653  1996.10 

  Date announced： 1998-120417  1998.05 

  Patent, Joint

Awards 【 Display / hide 】

Awards 【 Display / hide 】

• 平成29年度 特別研究員等審査会専門委員（書面担当）表彰

  2018.07, 独立行政法人 日本学術振興会

  Type of Award： Other

• CerSJ Fellow

  藤原 忍, 2017.06, 公益社団法人日本セラミックス協会

  Type of Award： Award from Japanese society, conference, symposium, etc.

• 日本セラミックス協会賞（学術賞）

  藤原 忍, 2015.06, 公益社団法人日本セラミックス協会, 無機発光材料の構造制御に基づく複合的光学機能の創出

  Type of Award： Award from Japanese society, conference, symposium, etc.

• Journal of the Ceramic Society of Japan, The Editor-in-Chief Award of Distinguished Reviewer

  藤原 忍, 2014.03, 日本セラミックス協会

• 日本セラミックス協会賞（進歩賞）

  藤原 忍, 2001.05, 社団法人日本セラミックス協会, ゾル－ゲル法による機能性フッ化物材料の創製に関する研究

  Type of Award： Award from Japanese society, conference, symposium, etc.

Courses Taught 【 Display / hide 】

Courses Taught 【 Display / hide 】

• SEMINAR IN APPLIED CHEMISTRY

  2024

• NANO SCALE SCIENCE JOINT SEMINAR

  2024

• MATERIAL SCIENCE 1

  2024

• MATERIAL DESIGN SCIENCE JOINT SEMINAR

  2024

• LABORATORIES IN APPLIED CHEMISTRY A

  2024

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Courses Previously Taught 【 Display / hide 】

Courses Previously Taught 【 Display / hide 】

• MATERIAL SCIENCE 3

  Keio University

  2018.04

  -

  2019.03

  , 

  Autumn Semester, Lecture, Within own ｆaculty

• DESIGN ENGINEERING OF FUNCTION IN MATERIALS

  Keio University

  2018.04

  -

  2019.03

  , 

  Autumn Semester, Lecture, Within own ｆaculty

• FUNDAMENTAL PHYSICAL CHEMISTRY 2

  Keio University

  2018.04

  -

  2019.03

  , 

  Autumn Semester, Lecture, Within own ｆaculty

• LABORATORIES IN APPLIED CHEMISTRY A

  Keio University

  2018.04

  -

  2019.03

  , 

  Spring Semester, Laboratory work/practical work/exercise, Within own ｆaculty

• DESIGN OF FUNCTIONAL MATERIALS

  Keio University

  2018.04

  -

  2019.03

  , 

  Spring Semester, Lecture, Within own ｆaculty

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Social Activities 【 Display / hide 】

Social Activities 【 Display / hide 】

• SDGsセッション：セラミックス分野のジェンダー主流化促進

  日本セラミックス協会男女共同参画委員会, 日本セラミックス協会2022年年会, 

  , 

  2022.03

• Women Researchers in STEM Fields– Isn’t it time to push for equal career promotion?

  Committee for Gender Equality, The Ceramic Society of Japan, The 13th Pacific Rim Conference of Ceramic Societies in Okinawa, 

  , 

  2019.10

• セラミックス大学2019（CEPRO2019）第3回講義「知って役立つ合成プロセス１：液相からの合成」

  日本セラミックス協会教育委員会

  2019.06

• CEPRO2018関西 第2回講義「液相からのセラミックス合成」

  日本セラミックス協会教育委員会・日本セラミックス協会関西支部

  2018.12

• セラミックス大学2018（CEPRO2018）第3回講義「知って役立つ合成プロセス１：液相からの合成」

  日本セラミックス協会教育委員会

  2018.06

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Memberships in Academic Societies 【 Display / hide 】

Memberships in Academic Societies 【 Display / hide 】

• The American Ceramic Society, 

  2008.11

  -

  Present

• The Electrochemical Society, 

  2008.04

  -

  Present

• 電気化学会, 

  2003.10

  -

  Present

• International Sol-Gel Society, 

  2003.07

  -

  Present

• The Japanese Sol-Gel Society, 

  2003.05

  -

  Present

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Committee Experiences 【 Display / hide 】

Committee Experiences 【 Display / hide 】

• 2019.06

  -

  Present

  委員長, 日本セラミックス協会／男女共同参画委員会

• 2019.06

  -

  Present

  男女共同参画理事, 日本セラミックス協会

• 2019.03

  -

  Present

  理事, 日本ゾルーゲル学会

• 2018.07

  -

  2020.07

  企画委員, 日本ゾル-ゲル学会

• 2015.06

  -

  2019.05

  副委員長, 日本セラミックス協会／男女共同参画委員会

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