Details of a Researcher - Miyamoto, Kazunori

Reviews, Commentaries, etc. - Miyamoto, Kazunori

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超原子価ハロゲン化合物イソスター（化学的等価体，疑似，mimic） Cross Dehydrogenative Coupling（CDC）反応室温りん光（RTP）

宮本和範, 内山真伸, 落合正仁, 森聡一朗, 羽田謙志郎, 柴田哲男, 伊藤彰近, 多田教浩, 山口英士, 谷洋介

有機合成化学協会誌 (公益社団法人有機合成化学協会) 81 ( 5 ) 527 - 527 2023.05

ISSN 0037-9980

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常温常圧下に発生させた二原子炭素の反応性の解明

宮本和範

上原記念生命科学財団研究報告集 (東京 : 上原記念生命科学財団) 37 1 - 5 2023

ISSN 2433-3441

Reply to “A Thermodynamic assessment of the reported room-temperature chemical synthesis of C<inf>2</inf>”

Miyamoto K., Narita S., Masumoto Y., Hashishin T., Osawa T., Kimura M., Ochiai M., Uchiyama M.

Nature Communications 12 ( 1 ) 2021.12

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Studies on multi-layered films of the hybrid system of arachidic acid and detonation nanodiamond (II)

Miura Yasuhiro, Akagi Yoshiya, Tanaka Toshihiko, Aoyama Tetsuya, Miyamoto Kazunori, Uchiyama Masanobu, Osawa Eiji

JSAP Annual Meetings Extended Abstracts (The Japan Society of Applied Physics) 2020.2 1485 - 1485 2020.08

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二原子炭素 : 一段階合成,たった2つの炭素,3種のナノカーボン,4つの結合

宮本和範, 内山真伸

現代化学 = Chemistry today (東京 : 東京化学同人) ( 593 ) 47 - 53 2020.08

ISSN 0386-961X

Silaboration of [1.1.1]Propellane: A Storable Feedstock for Bicyclo[1.1.1]pentane Derivatives

Masaki Kondo and Junichiro Kanazawa and Tomohiro Ichikawa and Takumi Shimokawa and Yuki Nagashima and Kazunori Miyamoto and Masanobu Uchiyama

Angewandte Chemie (Wiley) 132 ( 5 ) 1986 - 1990 2020.01

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Silaboration of [1.1.1]Propellane: A Storable Feedstock for Bicyclo[1.1.1]pentane Derivatives

Masaki Kondo and Junichiro Kanazawa and Tomohiro Ichikawa and Takumi Shimokawa and Yuki Nagashima and Kazunori Miyamoto and Masanobu Uchiyama

Angewandte Chemie International Edition (Wiley) 59 ( 5 ) 1970 - 1974 2020.01

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Studies on thin films of detonation nanodiamond fabricated at the air/water interface (Ⅲ)

Akagi Yoshiya, Miura Yasuhiro F., Tanaka Toshihiko, Aoyama Tetsuya, Miyamoto Kazunori, Uchiyama Masanobu, Osawa Eiji

JSAP Annual Meetings Extended Abstracts (The Japan Society of Applied Physics) 2019.2 2424 - 2424 2019.09

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超原子価で切拓く未踏ハロゲン化学

宮本和範, 落合正仁

現代化学 = Chemistry today (東京 : 東京化学同人) ( 529 ) 42 - 47 2015.04

ISSN 0386-961X

ヨウ素を金属代替元素とする触媒的酸化反応へのアプローチ

宮本和範

ファルマシア (公益社団法人日本薬学会) 48 ( 3 ) 237 - 237 2012

ISSN 0014-8601

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Hypervalent phenyl-λ3-iodane-mediated para-selective aromatic fluorinationof 3-phenylpropyl ethers

宮本和範

Chem.Commun. 3410 - 3412 2011

Weakly nucleophilic conjugate bases of superacids as powerful nucleophiles in vinylic bimolecular nucleophilic substitutions of simple β-alkylvinyl(aryl)-λ3-bromanes

宮本和範

J.Am.Chem.Soc. 133 3342 - 3344 2011

New Strategy for Baeyer-Villiger Oxidation: Reaction of Aromatic and Primary Aliphatic Aldehydes

Yoshimura Akira, Miyamoto Kazunori, Ochiai Masahito

Proceedings of the Symposium on Progress in Organic Reactions and Syntheses (Division of Organic Chemistry, The Pharmaceutical Society of Japan) 36 86 - 86 2010

A conceptually distinct, modern strategy for Baeyer-Villiger oxidation (BVO) was developed. Our novel method involves initial hydration of water to carbonyl compounds, followed by ligand exchange of hypervalent arylbromane on bromane(III) with the resulting hydrate, yielding a new type of activated Criegee intermediate. The intermediate undergoes BV rearrangement and produces an ester via facile reductive elimination of arylbromanyl group, because of the hypernucleofugality. The novel strategy makes it possible to induce selectively the BV rearrangement of straight chain primary aliphatic as well as aromatic aldehydes, which is missing in the classical BVO: for instance, octanal and benzaldehyde afforded rearranged formate esters with high selectivity (>95%) under our conditions, while the attempted their classical BVO produced only carboxylic acids. This firmly establishes the powerful nature of new methodology for BVO.